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I would, and have, brazed headers many times. Easy on your situation. Gas welding oxy/acytolene tip with brass flux rod. You can flow it into the tight space.
Because of the heat involved in those kind of situations, I use anti-seize that I buy from Ford that they sell for their 5.4 spark plug lube. Good stuff ! Again, if you would ever need to remove. Wouldn't be too concerned about exhaust pressure leak past a tight pipe plug.