I know the job is screwed up to start with, and not knowing much detail, here goes, so, any chance there is a shutoff (ball valve) above or below the circulator? Maybe the boiler is to small, water moving though to fast, not enough hot water heating surface? If you have a valve, close one valve halfway or a little more (never fully closed). This idea (I have used and it worked because the water was moving though the boiler to fast to get hot enough, the boiler was sized wrong for very bad weather), should slow the water flow, with the water coming out of the boiler being hotter and lasting longer. Yes, first served radiators will get hotter and maybe the water getting to the last radiator may be holding it's heat longer (because it is coming out of the boiler hotter). Or you cut a bypass pipe between the radiator's feed (enter) side and the return (exit) side and install your venturi tee, the correct way of the flow. Now you have just created a zig-zag main, (no real straight running main). And either way you have to drain the system and fight the dribble water to solder copper pipes and fittings, (I do not know what type of pipe you have) or cut and thread steel pipe. Some installers use the Viega PEX 3/4" oxygen barrier pipe with press tight rings and fitting's , (good up to 100 psi, at 180 degrees temperature). But you already know which way will work the best the first time and your done, even if it is difficult.
Just an after thought here, You say "you'll put the venturi in the radiator that is the problem". That just moves warm water into that last cold radiator. How about putting the venturi at the first few and hottest radiators, that way the hot water will split and go onto the next radiator in the line? That's all I have for now.
Dame halfa$$ plumber, probably was an out of work Dentist and looked on youtube at what to do.