What you seem to be tying your wagon to is the supposition that the two fuels being mixed interact chemically in some way with each other forming new compounds, and that accounts for the non-simple algebraic nonlinear new calculated octanes you have yet to share. I submit there is no chemical reaction taking place that the OP is considering, nor do the components of these two fuels counter each other in any way. Their effects are additive. This of course assumes the fuels are blendable, and somewhat easy to verify. If the components do not interact to form new compounds, it doesn't matter what the fuel is made of. You are welcome to make a case otherwise, I'm all ears.