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Pressure only raises the boiling point and has nothing to do with running cooler. Non vented cap? Didn't know you could even get one. What happens if you over pressure the radiator? Something is going to give and you hope a hose does it before you split the radiator. Put a dang douche bag on it and recover your coolant when it expands so it's not always leaving a puddle everywhere you go. Are you running a shroud on the radiator and what type of fan system does it have? Did you know straight water actually cools better than a 50/50 mix of antifreeze? WaterWetter is supposed to do a good job too. I have run straight water before with good results but you had better run a water pump lube and corrosion inhibitor in it. You can buy it as a mix too.
YES...Increasing the cooling system pressure increases the boiling point by 3 degrees F for every pound pressure increase. The specific heat characteristics of the the coolant is another factor. Specific heat is the ability of the coolant to absorb heat in the engine or heat source and subsequently releasing the absorbed heat in the radiator or heat exchanger. A 50% concentration of ethylene glycol and water combined with a 15# pressure cap increases the boiling point of the coolant to 265° F. YES...water is the better alternative and adding a "water wetter", which is an ionic surfactant, which decreases the surface tension of the water, promoting better heat transfer. A modern day water pump does not need a "water pump lubricant", as the pump's bearings are sealed and do not require lubricant. In the old days, the wster pump used a brass bushing and the lubricant was a water "soluble oil", which looked like milk. The modern pump does have a mechanical carbon vs ceramic shaft seal, which is lubricated by the coolant flow. However, if using just water as the coolant, a corrosion inhibitor and an antifoam additive (to refuce or eliminate water pump cavitation) is a definite must. My preference is a full strength coolant (ethylene glycol) with the corrosion inhibitors and I'll dilute it with my water to the 50% concentration rather than the pre-dilluted material, as my water is less expensive.
I believe the non-vented cap allows the use of a coolant recovery system, keeping the radiator 100% full, without any entrained air for better system performance. Just my opinion of course.
BOB RENTON