They don't settle once cured. What you're seeing is the difference in the "flop" of the metallic, and sometimes solid, particles in the material. And also the difference in the drying rate between metal and plastic. Your shape is plastic and when you painted it, it was on its wheels more or less. The flop is like fish scales. The way they settle, on the vertical areas will look different than horizontal areas and contours. It's truly the same but because of the position of the part when painted, it will look different when in a different position. Thats why when you paint parts, fenders/doors/hoods etc off the car, they need to be painted in their installed orientation. Look at your family late model ride, or others in a parking lot. Look at the front and rear bumpers. Look how they are against the quarters or front fender. They don't match 100%. Part of that is because they're plastic and the other is the position they were in when painted. At the shop I managed, it was a constant battle to get the painters to shoot the covers in the installed positions. The stands they used would rotate so they could. They were just lazy. Every time there was a mismatch when installed, the painter got to redo it for free or get back flagged.